超低水胶比水泥混凝土的自收缩特性及其机理
王 冲 , 王勇威 , 蒲心诚 , 叶建雄 , 白 光
(1.重庆大学材料科学与工程学院,重庆400045;2.山东省建筑科学研究院,山东济南250031)
摘要:测试了水胶比为0.1O~0.16水泥净浆及水胶比为0.16~0.50混凝土的自收缩,分析了石
灰石粉和龄期对超低水胶比水泥净浆自收缩的影响.结合水泥石孔结构与水化进程,探讨了超低水
胶比水泥混凝土的自收缩机理.结果表明:当水胶比≤0.16时,水泥净浆自收缩随水胶比的降低而
降低;当水胶比低于o.25时,混凝土自收缩随水胶比的减小而降低;当水胶比高于0.25时,混凝土
自收缩随水胶比的降低而增加;当水胶比为0.25(临界水胶比)时,混凝土的自收缩最大;磨细石灰
石粉可以很好抑制水泥净浆的自收缩;超低水胶比水泥净浆1 d龄期的自收缩可达到18O d龄期收
缩值的50 以上;超低水胶比水泥混凝土的自收缩特性与水泥石中孔结构以及水化进程有关.
关键词:超低水胶比水泥混凝土;自收缩;特性;机理
中图分类号:TU528.0 文献标志码:A doi:10.3969/j.issn.1007—9629.2010.01.O16
Characteristics and M echanisms for Autogenous Shrinkage of
Cement Concrete with Very Low W ater。Binder Ratio
WANG Chong , WANG Yong—wei , PU Xin—cheng , YE Jian—xiong , BAI Guang
(1.College of M aterial Science and Engineering,Chongqing University,Chongqing 400045,China;
2.Shandong Provincial Academy of Building Research,Jinan 250031,China)
Abstract:Autogenous shrinkage of cement paste with water-binder ratio(m(W )/m(B))of 0.10—0.16,and
of concrete with (W)/m(B)of 0.16—0.50 were measured,respectively.Influences of limestone powder
and age on autogenous shrinkage w ere studied. M echanism for autogenous shrinkage of cem ent concrete
with very low (W)/m(B)was analyzed by studying the pore structure and hydration progress of harden—
ed cement paste.The results show that the autogenous shrinkage of cement paste reduces with decrease of
(W )/m(B)in the case of m(W )m(B)≤ 0.16,the autogenous shrinkage of concrete reduces with de—
crease of m(W )/m(B)when优(W)/m(B)is 1ess than 0.25,but autogenous shrinkage of concrete increa—
ses with decrease of m(W)/m(B)when m(W )/m(B)is over 0.25.A critical (W )/m(B)of 0.25 is ob—
served in which autogenous shrinkage of concrete is biggest.Limestone powder is effective to restrain the
autogenous shrinkage of cement paste.The autogenous shrinkage of cement paste at 1 d age is above 5O%
of shrinkage value at 1 8O d. It is also concluded that m echanism for autogenous shrinkage of cem ent COD—
crete with very low m(W )/m(B)is related to pore structure and hydration progress of hardened cement
paste.
Key words:cement concrete with very low (W )/re(B);autogenous shrinkage;characteristic;mechanism
近年来,随着工程技术的要求与发展,高强、高
性能混凝土在研究与工程应用领域中日益受到重
视.混凝土强度增加的基础在于混凝土水胶比的降
低.水胶比低于0.2O(质量比,下同)的超高强混凝
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